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Effect of chemical reaction on particle to gas heat transfer
Affiliation:1. Department of Physics-Chemistry, University of Puerto Rico-Arecibo, P.O. Box 4010, Arecibo, PR 00613-4010. USA;2. Department of Chemistry, University of Puerto Rico-Mayaguez, Call Box 9000, Mayaguez, PR 00681-900. USA;3. College of Pharmacy, University of Florida, Gainesville, FL 32611. USA;4. Universidad del Atlántico, Facultad de Ciencias Básicas, Barranquilla, 080002, Colombia;5. Life Science Research Center (CICV), Universidad Simón Bolivar, Barranquilla 080002, Colombia;1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D center for Petrochemical Technology, Tianjin University, Tianjin 300072, PR China;2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, PR China;1. Instituto de Astronomía y Física del Espacio (IAFE), CONICET/UBA, Argentina;2. Royal Belgian Institute for Natural Sciences (RBINS), Operational Directorate Natural Environment, Belgium;3. Laboratoire d''Océanographie de Villefranche (LOV), UMR 7093, CNRS/UPMC, France;4. Flemish Institute for Technological Research (VITO), Belgium;2. Institute on Membrane Technology (ITM-CNR), Rende, Italy
Abstract:Particle to gas heat transfer studies were carried out by employing the endothermic cyclohexane dehydrogenation reaction. The calculated heat transfer coefficients were on the lower side of those previously reported in the literature for unreactive systems. Previous studies of other investigators with reactive systems suggest that particle to gas heat transfer coefficients may increase with exothermic reaction due to the product molecules leaving the catalyst surface with excess vibrational energy. For an endothermic reaction this effect would result in the calculation of a lower heat transfer coefficient.
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