Abstract: | A carbon fiber (CF)/polyetheretherketone (PEEK) composite was manufactured using hybrid fabrics composed of CF and PEEK fiber. The fiber/matrix interface was modified by low temperature oxygen plasma treatment. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform attenuated total reflection infrared spectroscopy (FTIR-ATR) were used to relate the roughness and the functionality of the CF surface with the interfacial adhesion strength of the CF/PEEK composite. Scanning electron micrographs showed that plasma treatment increased the roughness of the CF surface up to 3 min of plasma treatment time; and prolonged treatment resulted in overall smoothing. XPS results confirmed that increasing treatment time marginally increased surface functionality: treatment for more than 5 min decreased the surface functionality by removing the active site of the CF surface. In addition, flexural strength and interlaminarshear strength (ILSS) of the CF/PEEK composite were measured. Their maximum values were observed at 3 min of plasma treatment time as a result of surface roughening by plasma etching. The SEM results were correlated with mechanical properties of the CF/PEEK composite. |