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A screening test for anti-wear additives in a modified four-ball test
Authors:J Cazin  P Tqui  Y Lesieur
Abstract:Modern engine tests that evaluate the anti-wear properties of automotive engine oils are increasingly sophisticated and expensive, and often have relatively poor precision. The development of a simple, inexpensive, and reliable bench test to screen the anti-wear properties of fully formulated engine oils prior to their testing in engines is therefore very attractive. Numerous methods already exist, but they typically measure wear only at the end of the test by measuring the consequences of wear. The present paper describes an alternative approach, its purpose being the comparative evaluation of the anti-wear performance of lubricants throughout the test under variable load. A four-ball machine was used as a test rig for this work, and was equipped with instruments allowing study of the oil bath temperature, load applied to the balls, and the displacement of the load lever arm. The work presented focuses on a test procedure containing the following important elements: pre-ageing of oils, test start-up at very low load, incremental increases in load, stepwise increase in load, with each step sufficiently long to allow system equilibrium. Recording and analysis of the temperature and arm displacement curves permit the recognition of two distinct forms of wear: slow and gradual abrasive wear, and sudden and intense adhesive wear (scuffing). The presence and the intensity of the latter were found to have a direct relation with the anti-wear performance of candidate oils in the API Sequence VE engine test. The procedure ranked oils correctly in relation to their dithiophosphate concentration, correctly distinguished secondary and primary zinc dithiophosphates and, more interestingly, predicted the positive effects of some ashless anti-wear additives in accordance with results obtained in the Sequence VE.
Keywords:engine oils  anti-wear performance  bench tests  screening  four-ball  variable load  wear  ZnDTP  zinc dithiophosphates  in-test evaluation
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