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Enhanced the structure and optical properties for ZnO/PVP nanofibers fabricated via electrospinning technique
Authors:Ali Omar Turky  Ahmed Barhoum  Mohamed MohamedRashad  Mikhael Bechlany
Affiliation:1.Central Metallurgical Research and Development Institute,Cairo,Egypt;2.InstitutEuropéen des Membranes, UMR 5635 ENSCM UM CNRS,Université Montpellier,Montpellier,France;3.Department of Inorganic Nonmetallic Materials,University of Science and Technology Beijing,Beijing,China;4.Department of Materials and Chemistry,VrijeUniversiteit Brussel (VUB),Brussels,Belgium;5.Chemistry Department, Faculty of Science,Helwan University,Cairo,Egypt
Abstract:Zinc oxide/polyvinylpyrrolidone (ZnO/PVP) nanocomposite fibers with enhanced structural, morphological and optical properties were purposefully tailored using electrospinning technique. Meanwhile, ZnO nanoparticles (NPs),with particle size of ~50 nm, were synthesized using a co-precipitation method. The nanocomposite fibers were prepared by an electrospun solution of PVP containing ZnO NPs of 2, 4, 6 and 8 wt%. Evidently, the morphological, thermal and optical properties of the ZnO/PVP nanocomposite fibers were enhanced by dispersing ZnO NPs into PVP fibers. Typically, controlling the ZnO NPs content and their dispersibility (0–8 wt%) into PVP fibers result in improved the thermal stability (an increase of onset decomposition temperature by ~120 °C above pure PVP fibers) as well as the UV–Vis protection (reduction in UV transmission by 70%) and the photoluminescence properties (a sharp UV emission around 380 nm) Overall, based on the enhanced properties, the PVP/ZnO nanocomposite fibers can be considered a promise material in optoelectronic sensors and UV photoconductor.
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