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Impacts of the subsurface storage of natural gas and hydrogen mixtures
Affiliation:1. Silesian University of Technology, 2 Akademicka St., 44-100, Gliwice, Poland;2. Mineral and Energy Economy Research Institute of the Polish Academy of Sciences, 7A J. Wybickiego, 31-261, Kraków, Poland;1. Department of Chemical & Petroleum Engineering, Faculty of Engineering, Technology and Built Environment, UCSI University, No.1, Jalan Menara Gading, UCSI Heights (Taman Connaught), Cheras, 56000 Kuala Lumpur, Malaysia;2. Center of Integrative Petroleum Research (CIPR), College of Petroleum Engineering and Geoscience, King Fahd University of Petroleum and Minerals, Saudi Arabia;3. Department of Petroleum Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, 32610, Perak, Malaysia;4. Physical Science and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955, Saudi Arabia;5. CSIRO Energy, Perth, Australia;1. Department of Chemical and Petroleum Engineering, University of Calgary, 2500, University Drive, Calgary, Canada;2. Petroleum Exploration and Production Research Institute, SINOPEC, No.31, Xueyuan Road, Beijing, China;3. School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, Australia;1. University of Edinburgh, School of Geosciences, Grant Institute, West Main Road, Edinburgh, EH9 3JW, UK;2. Institute of Petroleum Engineering, Heriot-Watt University, Riccarton Campus, Edinburgh EH14 4AS, UK
Abstract:The subsurface storage of hydrogen (H2) provides a potential solution for load-balancing of the intermittent electricity production from renewable energy sources. In such technical concept, surplus electricity is used to power electrolyzers that produce H2, which is then stored in subsurface formations to be used at times when renewable electricity is not available. Blending H2 with natural gas (NG) for injection into depleted gas/oil reservoirs, which are already used for NG storage, is considered a good option due to the lower initial capital cost and investment needed, and potential lower operating costs. In this study, the potential impact of storing a mixture of H2 and NG in an existing NG storage field was investigated. Relevant reservoir, caprock and cement samples from a NG storage formation in California were characterized with respect to their permeability, porosity, surface area, mineralogy and other structural characteristics, before and after undergoing 3-month incubation experiments with H2/NG gas mixtures at relevant temperature and pressure conditions. The results indicated relatively small changes in porosity and mineralogy due to incubation. However, the observed changes in permeability were more dramatic. In addition, polymeric materials, similar to those used in NG storage operations were also incubated, and their dimensions were measured before and after incubation. These measurements indicated swelling due to the exposure to H2. However, direct evidence of geochemical reactions involving H2 was not observed.
Keywords:Power-to-Gas  Hydrogen subsurface storage  High temperature high pressure experiments  Cement  Caprock  Polymeric materials
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