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Rational design and fabrication of surface tailored low dimensional Indium Gallium Nitride for photoelectrochemical water cleavage
Affiliation:1. Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur, 603203, India;2. Electrochemical Materials Science and Functional Materials Division, CSIR-Central Electrochemical Research Institute, Karaikudi, India;3. Department of Physics, Faculty of Science, University of Zanjan, Zanjan, 45371-38791, Iran;4. Department of Biomedical Engineering, Chennai Institute of Technology, Tamilnadu, 600069, India;5. Crystal Growth Centre, Anna University, Chennai, 600025, India;1. TJU-NIMS International Collaboration Laboratory, School of Materials Science and Engineering, Tianjin University, Nankai District, Tianjin 300072, PR China;2. Fujian Provincial Key Laboratory of Functional Materials and Applications, School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, PR China;1. Centre for Nanoscience and Nanotechnology, School of Physics, Bharathidasan University, Tiruchirappalli, 620024, Tamil Nadu, India;2. UGC-DAE Consortium for Scientific Research (CSR), Kalpakkam Node, Kokilamedu, 603104, Tamil Nadu, India;1. Centre for Clean Energy and Nano Convergence, Hindustan Institute of Technology and Science, Chennai, India;2. Crystal Growth Centre, Anna University, Chennai, India;1. Optoelectronics Convergence Research Center, Chonnam National University, 77 Yong-bong-ro, Buk-gu, Gwangju, 61186, Republic of Korea;2. Department of Physics and Photon Science, Gwangju Institute of Science and Technology, Gwangju, 61005, Republic of Korea;3. Institute of Advanced Composite Materials, Korea Institute of Science and Technology, Joellabuk-do, 55324, Republic of Korea;4. Advanced Photonics Technology Development Group, School of Engineering, Center for Advanced Photonics, RIKEN, Japan;5. Materials Science and Engineering, Dong-A University, Busan, 49315, Republic of Korea;1. Department of Photonics and Advanced Optoelectronic Technology Center, National Cheng Kung University, Tainan City 70101, Taiwan;2. Department of Electro-Optical Engineering, Southern Taiwan University of Science and Technology, Tainan City 71001, Taiwan
Abstract:Currently several type of energy sources exist in the modern world. The energy makes people's life more comfortable, easy, time savings, fast transformation of information and various modes of transmission. Because of large demand of energy, efforts on production of energy increases day by day which subsequently increase serious environmental concerns such as pollution and lack of existing natural resources. In this respect, several attempts have been proposed for new type of renewable and chemical energy systems to overcome the economic burden, global warming and environmental problems caused by the use of conventional fossil fuels. Hydrogen production via water splitting is a promising and ideal route for renewable energy using the most abundant resources of solar light and water. Cost effective photocatalyst for Photoelectrochemical (PEC) water splitting using semiconductor materials as light absorbers have been extensively studied due to their stability and simplicity. Over the past few decades, various metal oxide photocatalysts for water splitting have been developed and their photocatalytic application was studied under UV irradiation. Alternative semiconductor photocatalyst should harness solar energy in the visible light, one such semiconductor material is indium gallium nitride (InGaN), owing to its suitable and tunable energy band-gap, chemical resistance and notable photoelectrocatalytic activity. This review article is initiated with the brief introduction about the origin and methods of production of hydrogen gas from both renewable and nonrenewable energy sources. Multi-functional properties and applications of InGaN are described along with past and recent efforts of InGaN materials for hydrogen evolution by several investigators are provided in detail. In addition, future prospects and ways to improve the PEC performance of InGaN are presented at the end of this review.
Keywords:Clean energy  Hydrogen production  PEC cell  Water splitting  InGaN  III-nitride semiconductor
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