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Thermodynamic analysis of fossil fuels reforming for fuel cell application
Affiliation:1. School of Civil Engineering and Architecture, Wuhan University of Technology, Wuhan, 430070, China;2. School of Energy and Power Engineering, Wuhan University of Technology, Wuhan, 430063, China;3. School of Mechanical & Mining Engineering, The University of Queensland, QLD, 4072, Australia;1. Fluid System Engineering Department, KEPCO Engineering and Construction Company, Taejeon, 34057, Republic of Korea;2. Department of Safety Engineering, Incheon National University, Incheon, 22012, Republic of Korea;3. Fire Disaster Prevention Research Center, Incheon National University, Incheon 22012, Republic of Korea;4. Department of Mechanical Engineering, Hannam University, Taejeon, 34430, Republic of Korea;1. College of Safety Science and Engineering, Nanjing Tech University, Nanjing, 210009, China;2. Jiangsu Key Laboratory of Urban and Industrial Safety, Nanjing Tech University, Nanjing, 210009, China;1. School of Energy Resources, China University of Geosciences, Beijing, 100083, PR China;2. Sinopec Southwest Oil and Gas Branch of the Gas Plant, Chongqing, 402160, PR China
Abstract:At present, the infrastructure of hydrogen production, storage and transportation is poor. Fuel reforming for hydrogen production from liquid fossil fuels such as kerosene, petrol and diesel is of great significance for wide application of on-board fuel cell and distributed energy resources. In this work, the produced and heat released of kerosene, petrol and diesel reformed by different reforming methods (autothermal reforming, partial oxidation, steam reforming) were studied by means of thermodynamic analysis. Based on the thermodynamic analysis, the effect of reforming methods on the system's ideal thermal efficiency are analysed. The results show that the hydrogen concentration of syngas obtained from steam reforming is highest regardless of the fuel types. The hydrogen yielded by per unit volume of diesel is largest under same reforming method. Autothermal reforming has the largest ideal thermal efficiency among three reforming methods.
Keywords:Reforming methods  Petrol  Kerosene  Diesel
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