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Simulation and optimization of hydrogen production by steam reforming of natural gas for refining and petrochemical demands in Lebanon
Affiliation:1. Department of Chemical Engineering, International Campus, University of Sistan & Baluchestan, Chabahar, Iran;2. Department of Chemistry, University of Eastern Finland, 111, FI80101 Joensuu, Finland;3. Department of Chemical Engineering, University of Sistan and Baluchestan, Zahedan 98164, Iran;4. Department of Chemical Engineering, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran
Abstract:Steam reforming of natural gas produces the majority of the world's hydrogen (H2) and it is considered as a cost-effective method from a product yield and energy consumption point of view. In this work, we present a simulation and an optimization study of an industrial natural gas steam reforming process by using Aspen HYSYS and MATLAB software. All the parameters were optimized to successfully run a complete process including the hydrogen production zone units (reformer reactor, high temperature gas shift reactor HTS and low temperature gas shift reactor LTS) and the purification zone units (absorber and methanator). Optimum production of hydrogen (87,404 MT/year) was obtained by fixing the temperatures in the reformer and the gas shift reactors (HTS & LTS) at 900 °C, 500 °C and 200 °C respectively while maintaining a pressure of 7 atm, and a steam to carbon ratio (S/C) of 4. Moreover, ~99% of the undesired CO2 and CO gases were removed in the purification zone and a reduction of energy consumption of 77.5% was reached in the heating and cooling units of the process.
Keywords:Natural gas steam reforming  Hydrogen  Hydro-processing  Petrochemicals  Process simulation  Process optimization  WGS"}  {"#name":"keyword"  "$":{"id":"kwrd0045"}  "$$":[{"#name":"text"  "_":"water gas shit  HTS"}  {"#name":"keyword"  "$":{"id":"kwrd0055"}  "$$":[{"#name":"text"  "_":"high temperature shift reactor  LTS"}  {"#name":"keyword"  "$":{"id":"kwrd0065"}  "$$":[{"#name":"text"  "_":"low temperature shift reactor  S/C"}  {"#name":"keyword"  "$":{"id":"kwrd0075"}  "$$":[{"#name":"text"  "_":"steam to carbon ratio  G/L"}  {"#name":"keyword"  "$":{"id":"kwrd0085"}  "$$":[{"#name":"text"  "_":"acid gas liquid ratio  MEA"}  {"#name":"keyword"  "$":{"id":"kwrd0095"}  "$$":[{"#name":"text"  "_":"mono-ethanol amine  NG"}  {"#name":"keyword"  "$":{"id":"kwrd0105"}  "$$":[{"#name":"text"  "_":"natural gas  SMR"}  {"#name":"keyword"  "$":{"id":"kwrd0115"}  "$$":[{"#name":"text"  "_":"steam methane reforming
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