Ultra-fast dehydrogenation behavior at low temperature of LiAlH4 modified by fluorographite |
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| Affiliation: | 1. State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;2. Institute of Chemical Defense, Academy of Military Science, Beijing 102205, China;3. Guangdong Provincial Key Laboratory of Advance Energy Storage Materials, South China University of Technology, Guangzhou 510640, China;4. Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Hangzhou 310013, China;1. State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China;2. Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Hangzhou 310013, PR China;1. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China;2. Water Affairs Research Institute, North China University of Water Resource and Electric Power, Zhengzhou, 450000, China;3. Shandong Jiaotong University, Jinan, 250357, China;1. State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;2. Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Hangzhou 310013, China;3. Guangdong Provincial Key Laboratory of Advance Energy Storage Materials, South China University of Technology, Guangzhou, 510640, China |
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| Abstract: | LiAlH4 modified by different weight ratios of fluorographite (FGi) can be synthesized through mechanical ball-milling and their dehydrogenation behaviors were investigated. LiAlH4 particles distributed on the FGi surface with greatly decreased sizes are achieved, comparing with ball-milled pristine LiAlH4. Greatly reduced dehydrogenation temperatures are discovered in LiAlH4-FGi composites. Among these composites, LiAlH4-40FGi composite exhibits an ultra-fast hydrogen release at very low temperature as 61.2 °C, and 5.7 wt% hydrogen is liberated in seconds. Besides, the released hydrogen is of high purity according to MS test. Furthermore, XRD analysis on the dehydrogenated products proves that FGi changes the dehydrogenation reaction pathway of LiAlH4, through which the dehydrogenation reaction enthalpy change is remarkably reduced, leading to greatly improved hydrogen desorption properties. Such investigations have discovered the potential of solid-state way of producing hydrogen under ambient temperatures. |
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| Keywords: | Fluorographite Hydrogen storage Destabilization |
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