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Study on solid waste pyrolysis coke catalyst for catalytic cracking of coal tar
Affiliation:1. State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. University of Chinese Academy of Sciences, Beijing 100190, China;3. Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Abstract:Low value solid waste pyrolysis coke was used as a catalyst to catalytically crack gas-phase tar to improve tar yield and gas production. Pyrolysis coke with different pyrolysis final temperature and pyrolysis time were prepared, the effect of tar cracking products was studied, and the optimal pyrolysis coke were screened. The pyrolysis coke catalyst was characterized by BET, FTIR, SEM. The results show that the optimal preparation final temperature of pyrolysis coke is 750 °C, and the optimal preparation pyrolysis time is 2 h. Compared with the pyrolysis of raw coal, the tar cracking rate increased by 9.3%, after added the pyrolysis coke catalyst, the gas increased by 23.2%, and the light component increased to 36.6%. And the OH, C–N and C–O–C functional groups present on coke are the factors that affect the catalytic cracking.
Keywords:Pyrolysis coke  Catalytic cracking  Gas production  Light component  Resource utilization
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