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A Novel Synthesis Route of Butyric Acid from Hydrogenation of Maleic Anhydride over Pd/TiO2 Catalysts
Authors:Jian Xu  Kunpeng Sun  Li Zhang  Yunlai Ren  Xianlun Xu
Affiliation:(1) State Key Laboratory for Oxo Synthesis Slective Oxidation, Lanzhou Institute of Chemical physics, Chinese Academy of Sciences, Lanzhou, 730000, China;(2) PetroChina Lanzhou Lubricating oil R&D Institute, Lanzhou, 730060, China
Abstract:A highly efficient Pd/TiO2 catalyst for the liquid phase hydrogenation of maleic anhydride has been prepared by sol–gel method, and super critical fluid of ethanol drying (SCFE) was applied. The catalyst exhibited excellent activity and high yield to butyric acid. The structural properties of TiO2 supported Pd catalyst were investigated by BET, TEM, XRD, XPS and TPR techniques with the aim of finding a correlation between the structure parameters and the catalytic activities.
Keywords:maleic anhydride  butyric acid  hydrogenation  Pd/TiO2  sol–  gel
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