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Superconductivity at 103 K in CdBa2(Ca0.7Y0.3)Cu2Oy
Authors:N Balchev  V Lovchinov  E Gattef  A Staneva  K Konstantinov and J Pirov
Affiliation:(1) Institute of Solid State Physics, 1784 Sofia, Bulgaria;(2) Higher Institute of Chemical Technical Technology, 1156 Sofia, Bulgaria;(3) Institute of General and Inorganic Chemistry, 1040 Sofia, Bulgaria;(4) Electroheat Ltd., Botunetz District, 1870 Sofia, Bulgaria
Abstract:A cadmium analogue of the mercury system with nominal composition CdBa2(Ca1–xYx)Cu2Oy has been synthesized. Thex=0 samples contain about 12 vol.% of the 1212 phase but are not superconducting. Thex=0.3 samples are superconducting atT on = 103 K. The EDX analysis of 18 microcrystals shows a broad cationic distribution of the different components. The observed broad superconducting transition is attributed to the variousT c of the different microcrystals.
Keywords:CdBa2(Ca0  7Y0  3)Cu2Oy  superconductivity
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