| 高锰酸钾氧化法制备4-（4′-正丙基环己基）环己酮 |
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| 引用本文： | 杨永忠,安彦彦,余勇,李荣霞,方大伟,孙国辉.高锰酸钾氧化法制备4-（4′-正丙基环己基）环己酮[J].山东化工,2009,38(11):10-12. |
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| 作者姓名： | 杨永忠 安彦彦 余勇 李荣霞 方大伟 孙国辉 |
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| 作者单位： | 西安瑞联近代电子材料有限公司,陕西西安,710077 |
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| 摘 要： | 4-（4′-正丙基环己基）环己酮是一种重要的液晶中间体,本文用高锰酸钾氧化丙基环己基环己醇制备出了4-（4′-正丙基环己基）环己酮，并考察了溶剂，温度及酸用量对反应的影响，制得的目标产物气相含量为99．49％，杂质峰小于0．5％，并对目标产物的结构进行了红外光谱，气质谱及核磁共振碳谱的测定。
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| 关 键 词： | 高锰酸钾 氧化 4-(4′-正丙基环己基)环己酮 |
Synthesis of 4 - (4'- Propylcyclohexyl) Cyclohexanone Oxidation with Potassium Permanganate |
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| YANG Yong-zhong,AN Yan-yan,YU Yong,LI Rong-Xia,FANG Da-Wei,SUN Guo-hui.Synthesis of 4 - (4'- Propylcyclohexyl) Cyclohexanone Oxidation with Potassium Permanganate[J].Shandong Chemical Industry,2009,38(11):10-12. |
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| Authors: | YANG Yong-zhong AN Yan-yan YU Yong LI Rong-Xia FANG Da-Wei SUN Guo-hui |
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| Affiliation: | YANG Yong-zhong,AN Yan-yan,YU Yong,LI Rong-Xia,FANG Da-Wei,SUN Guo-hui(Xi'an Ruilian Modern Electronic Chemicals Co.,Ltd.,Xi'an 710077,China) |
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| Abstract: | 4 - （ 4′ - propylcyclohexyl） cyclohexanone was prepared from 4 - （ 4′ - propylcyclohexyl） cyclohexanol . KMO4 was the oxidant in the solvent of acetone and ethylene dichloride at the temperature of 20℃. The content of the product by GC was 99.49 %. Structure of the compound was determined by IR,13C- NMR and GC -MS. The synthesized substance could be used as an important intermediate for multi -ring system liquid crystal compounds. |
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| Keywords: | potassium permanganate oxidation 4-(4'-propylcyclohexyl)-cyclohexanone |
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