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Separation of indium (Ⅲ), gallium (Ⅲ), and zinc (Ⅱ) with Levextrel resin containing di(2-ethylhexyl) phosphoric acid (CL-P204): Part I. Selection of separation conditions
作者姓名:LIU Junshen  HE Zhengguang  CAIJun  CAI Chunguang  ZHOU Baoxue  and CAI Weimin1) Department of Environmental Science and Engineering  Harbin Institute of Technology  Harbin  150090  China2) School of Environmental Science and Engineering  Shanghai Jiaotong University  Shanghai 200240  China
作者单位:LIU Junshen,HE Zhengguang,CAIJun,CAI Chunguang,ZHOU Baoxue,and CAI Weimin1) Department of Environmental Science and Engineering,Harbin Institute of Technology,Harbin,150090,China2) School of Environmental Science and Engineering,Shanghai Jiaotong University,Shanghai 200240,China
摘    要:A kind of Levextrel resin separation process was developed for separation of indium (Ⅲ), gallium (Ⅲ), and zinc (Ⅱ) from aqueous sulfate solution with Levextrel resin containing di(2-ethylhexyl) phosphoric acid (CL-P204). The aim of the research is to collect preliminary results for a pilot-scale production. Properties of adsorbing indium (Ⅲ), gallium (Ⅲ), and zinc (Ⅱ) from sulfate solution with the Levextrel resin were first studied by batch operation and column operation. The optimum pH, adsorption capacities and concentrations of stripping agents for indium (Ⅲ), gallium (Ⅲ) were tested. The separation order of indium (Ⅲ), gallium (Ⅲ), and zinc (Ⅱ) from sulfate solution with CL-P204 Levextrel resin was found that indium (Ⅲ) could be first separated by adsorbing at the acidity of 1.0 mol/L whereas gallium (Ⅲ) and zinc (Ⅱ) could not, and they were adsorbed together by adsorbing at pH = 2.8, then separated from each other by stripping with 0.1 and 0.5 mol/L hydrochloric acid, respectively. T

关 键 词:inorganic chemistry engineering  separation  Levextrel resin separation  indium (Ⅲ)  gallium (Ⅲ)  zinc (Ⅱ)
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