| 油酸异丙酯的合成及其对生物柴油低温流动性研究 |
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| 引用本文： | 李静,李法社,徐娟,樊志龙.油酸异丙酯的合成及其对生物柴油低温流动性研究[J].广东化工,2011,38(6):5-6. |
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| 作者姓名： | 李静 李法社 徐娟 樊志龙 |
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| 作者单位： | 1. 西南林业大学,基础部,云南,昆明,650224
2. 昆明理工大学,云南,昆明,650993 |
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| 摘 要： | 油酸与异丙醇在对甲苯黄酸催化剂的作用下发生酯化反应制备油酸异丙酯。单因素研究催化剂用量、醇酸配比、反应时间、反应温度等对酯化反应得率的影响规律,并通过测定凝固点、冷滤点、粘度来考察脂肪酸异丙脂对生物柴油的降凝效果。结果表明,催化剂的量3%,醇酸体积比2∶1（摩尔比8.2∶1）,反应温度80℃,反应时间4 h,酯化率达到90.5%。降凝实验结果表明把一定量的脂肪酸异丙酯添加到生物柴油中可有效地降低生物柴油的凝固点、冷滤点,改善其低温流动性能。
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| 关 键 词： | 酯化反应 油酸异丙酯 生物柴油 低温流动性 |
Synthesis and Effect of Oleic Acid Isopropyl Ester on Cold Flow Properties for Biodiesel |
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| Li Jing,Li Fashe,Xu Juan,Fan Zhilong.Synthesis and Effect of Oleic Acid Isopropyl Ester on Cold Flow Properties for Biodiesel[J].Guangdong Chemical Industry,2011,38(6):5-6. |
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| Authors: | Li Jing Li Fashe Xu Juan Fan Zhilong |
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| Affiliation: | Li Jing1,Li Fashe2,Xu Juan1,Fan Zhilong1(1.The Basis of the Department of Southwest Forestry University,Kunming 650224,2.Kunming University of Science and Technology,Kunming 650093,China) |
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| Abstract: | Oleic acid isopropyl ester was produced by the esterification of oleic acid with Isopropyl alcohol in the presence of P-toluene sulfonic acid catalysts.The effect of preparation conditions such as the amount of catalyst and isopropyl alcohol,reaction temperature and time on the yield of isopropyl alcohol ester and the effect of oleic acid isopropyl ester on reducing pour point of biodiesel were reviewed.The investigation on synthesis of oleic acid isopropyl ester shows that the mass fraction of catalyst was... |
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| Keywords: | esterification reaction isoproyloleic biodiesel cold flow properties |
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