| 层状铌基复合氧化物固体酸及其醋酸正丁醇酯化的催化活性 |
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| 引用本文： | 唐元,何杰,张忠良,李安,蔡威盟. 层状铌基复合氧化物固体酸及其醋酸正丁醇酯化的催化活性[J]. 广东化工, 2011, 38(5): 67-68,66 |
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| 作者姓名： | 唐元 何杰 张忠良 李安 蔡威盟 |
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| 作者单位： | 安徽理工大学化学工程学院;南京大学扬州化学化工研究院; |
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| 基金项目： | 安徽省自然科学基金(11040606M38) |
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| 摘 要： | 采用固相法合成出具有典型层状结构的LiNbMoO<,6>、LiNbWO<,6>和KTiNbO<,5>,并通过离子交换法获得HNbMoO<,6>、HNbWO<,6>和HTiNbO<,5>.采用X-射线粉末衍射(XRD)、扫描电镜(SEM)、NH<,3>程序升溢热脱附(NH<,3>-TPD)等技术对其进行表征.通过醋酸与正...
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| 关 键 词： | 锐钼酸 铌钨酸 钛铌酸 酯化反应 |
Esterification of Acetic Acid and Butanol Catalyzed by Layered Niobium Matrix Composite Oxides Solid Acid |
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| Tang Yuan,He Jie,Zhang Zhongliang,Li An,Cai Weimeng. Esterification of Acetic Acid and Butanol Catalyzed by Layered Niobium Matrix Composite Oxides Solid Acid[J]. Guangdong Chemical Industry, 2011, 38(5): 67-68,66 |
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| Authors: | Tang Yuan He Jie Zhang Zhongliang Li An Cai Weimeng |
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| Affiliation: | Tang Yuan1,2,He Jie1,Zhang Zhongliang2,Li An1,Cai Weimeng1(1.School of Chemical Engineering,Anhui University of Science and Technology,Huainan 232001,2.Nanjing University Yangzhou Institute of Chemistry and Chemical Engineering,Yizheng 211400,China) |
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| Abstract: | Layered HNbMoO6、HNbWO6 and HTiNbO5 were prepared through ion-exchange by LiNbMoO6、LiNbWO6 and KTiNbO5 respectively,which were synthesized by solid method.The samples were characterized by X-ray diffraction(XRD)、Scanning electron microscope(SEM)、NH3 temperature-programmed desorption(NH3-TPD).Esterification of acetic acid and butanol catalyzed by HNbMoO6、HNbWO6 and HTiNbO5.The results showed that neither HNbWO6 nor HTiNbO5 catalyzed esterification of acetic acid and butanol.Which may be attributed to reactant shape-selecting of their narrow interlayer;HNbMoO6 presents well esterification activity.Because the interlayer of HNbMoO6 was wide and it can intercalate the butanol.Moreover,the strong surface acidity can improve esterification activity of catalyst. |
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| Keywords: | HNbMoO6 HNbWO6 HTiNbO5 Esterification |
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