Preparation of Mn?Zn ferrite from spent zinc-carbon batteries by alkali leaching,acid leaching and Co-precipitation |
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Authors: | Tae-Hyun Kim Jin-Goo Kang Jeong-Soo Sohn Kang-In Rhee Seoung-Won Lee Shun-Myung Shin |
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Affiliation: | (1) Minerals and Materials Processing Division, Korea Institute of Geoscience and Mineral Resources, Gwahang-no 92, Yuseong-gu, 305-350 Daejeon, Korea;(2) Resource Recycling, University of Science & Technology (UST), 52, Eoeun-dong Yuseong-gu, 305-333 Daejeon, Korea;(3) Department of Nano Materials, Chungnam National University, 220, Gung-dong, Yuseong-gu, 305-764 Daejeon, Korea |
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Abstract: | The treatment of spent zinc-carbon batteries for the recovery of valuable metals followed by conversion to Mn−Zn ferrite has
been conducted employing two-stage alkali and acid leaching and co-precipitation method. In the first stage, leaching process
was carried out with 4 M NaOH, which resulted in a recovery of 63.4 %Zn and 0.1% Mn. Electrowinning of alkali leaching solution
containing 12.75 g/L Zn at a current density of 0.2 A/cm2 produced Zn metal of 15 nm to 30 nm size and 99.9% purity. The second stage leaching of residue with 3 M H2SO4 and 6 vol.% H2O2 at a solid/liquid ratio of 1∶10 indicated the leaching efficiency of 98.0% Zn, 97.9% Mn and 55.2% Fe. The obtained leaching
solution was finally adjusted to suitable mole ratios of Mn∶Zn∶Fe (1∶1∶4) by the addition of Zn and Fe sulfate salts followed
by pH control to produce Mn−Zn ferrite powder. The characterization of the ferrite powder showed uniform nano-crystalline
particles of about 20 nm size with spinel structure. |
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Keywords: | spent zinc-carbon battery NaOH leaching Zinc H2SO4 leaching Mn− Zn ferrite powder |
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