| 磷酸酯及膦酸酯化学键的辐射稳定性研究 |
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| 引用本文： | 盛怀禹 何永海. 磷酸酯及膦酸酯化学键的辐射稳定性研究[J]. 辐射研究与辐射工艺学报, 1989, 7(2): 42-50 |
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| 作者姓名： | 盛怀禹 何永海 |
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| 作者单位： | 中国科学院上海有机化学研究所，中国科学院上海有机化学研究所，中国科学院上海有机化学研究所，中国科学院上海有机化学研究所，中国科学院上海原子核研究所，中国科学院上海原子核研究所，中国科学院上海有机化学研究所，中国科学院上海有机化学研究所 上海，上海，上海，上海，上海，上海 |
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| 摘 要： |
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| 关 键 词： | 磷酸酯 膦酸酯 稳定性 化学键 |
A STUDY ON RADIATION STABILITY OF CHEMICAL BONDS IN ORGANIC PHOSPHATES AND PHOSPHONATES |
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| Sheng Huaiyu,He Yonghai,Wang Zhizhang,Chen Yaoguan,Liu Renzhong,Tu Tiechen,Wang Qizhong,Yuan Shengang. A STUDY ON RADIATION STABILITY OF CHEMICAL BONDS IN ORGANIC PHOSPHATES AND PHOSPHONATES[J]. Journal of Radiation Research and Radiation Processing, 1989, 7(2): 42-50 |
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| Authors: | Sheng Huaiyu He Yonghai Wang Zhizhang Chen Yaoguan Liu Renzhong Tu Tiechen Wang Qizhong Yuan Shengang |
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| Affiliation: | Sheng Huaiyu,He Yonghai,Wang Zhizhang,Chen Yaoguan,Liu Renzhong,Tu Tiechen,Wang Qizhong,Yuan Shengang Shanghai Institute of organic chemistry,Academia Sinica,Shanghai |
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| Abstract: | The radiation stability of various chemical bonds of organic phospha-tes and phosphonates were studied by using of low-temperature (77K) ESR measure-ment of radicals formed in gamma-irradiated samples at 77 K, and by using of MSspectral analysis and the partial charges of atoms calculated by iterative partial equli-zation of orbital electronegativity. |
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| Keywords: | Phosphates Phosphonates Radiation stability Partial charge of atoms calculation Low temperature ESR spectrium |
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