Anionic polymerization of vinylsilanes |
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| Authors: | Oku Jun-ichi Hasegawa Takashi Kubota Yoshiharu Takaki Mikio Asami Ryuzo |
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| Affiliation: | (1) Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466 Nagoya, Japan |
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| Abstract: | Summary The anionic polymerization of dimethylphenylvinylsilane with sec-butyllithium/N,N,N ,N-tetramethylethylenediamine (TMEDA) was investigated. The polymerization proceeded up to 100% yield and afforded the polymer having isomerized-structure units. The polymerization was accompanied by chain transfer reaction to the monomer and the polymerization rate in the presence of TMEDA was much lower than in the absence of TMEDA. |
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