| 苯薄荷醇衍生物和萘薄荷醇衍生物的合成与表征 |
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| 引用本文： | 麦尔布合·阿布都热西提,迪丽菲嘎尔·阿布都热一木.苯薄荷醇衍生物和萘薄荷醇衍生物的合成与表征[J].化学试剂,2009,31(3). |
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| 作者姓名： | 麦尔布合·阿布都热西提 迪丽菲嘎尔·阿布都热一木 |
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| 作者单位： | 新疆师范大学,生命科学与化学学院,新疆,乌鲁木齐,830054 |
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| 摘 要： | 主要研究二环4.2.0]辛酮中间体薄荷醇衍生物的合成工艺.以(-)-1 R,2S,5R-8-苯薄荷醇和(-)-1R,2S,5R -8-萘薄荷醇为原料,通过酯化反应合成目标化合物,产率分别为58.7%、92%.其结构经 1HNMR、13CNMR进行了表征,并对标题化合物的构象稳定性和晶体结构进行了研究.
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| 关 键 词： | 苯薄荷醇衍生物 萘薄荷醇衍生物 合成 表征 |
Synthesis and characterization of phenyl menthol derivatives and naphthyl menthol derivatives |
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| Maierbuha ABUDUREXITI,Dilfeigaer ABUDOUREYIMU.Synthesis and characterization of phenyl menthol derivatives and naphthyl menthol derivatives[J].Chemical Reagents,2009,31(3). |
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| Authors: | Maierbuha ABUDUREXITI Dilfeigaer ABUDOUREYIMU |
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| Affiliation: | Institute of Life Science and Chemistry;Xinjiang Normal University;Urumqi 830054;China |
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| Abstract: | The process for synthesis of bicyclic octanone intermediates the menthol derivatives was studied.(-)-1R,2S,5R-8-Phenyl menthol and(-)-1R,2S,5R-8-(2-naphthyl) menthol were chosen as raw materials,and the title compounds were synthesized via esterification,with the total yield equating to 58.7% and 92%,respectively.The structures of these compounds were characterized by 1HNMR,and 13CNMR.The studies on the stability and crystal structure of the compounds 2a and 2b were conducted. |
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| Keywords: | phenyl menthol derivatives naphthyl menthol derivatives synthesis characterization |
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