| Sb掺杂对Mg_2Si基化合物热电性能的影响(英文) |
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| 引用本文： | 张倩,赵新兵,殷浩,朱铁军.Sb掺杂对Mg_2Si基化合物热电性能的影响(英文)[J].稀有金属材料与工程,2009,38(Z1). |
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| 作者姓名： | 张倩 赵新兵 殷浩 朱铁军 |
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| 作者单位： | 浙江大学,硅材料国家重点实验室,浙江,杭州,310027 |
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| 基金项目： | 国家重点基础研究发展规划(973计划)，国家自然科学基金，the Education Ministry of China |
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| 摘 要： | 采用感应熔炼和真空热压的方法制备了Sb掺杂和未掺杂的Mg2Si基热电材料.研究了Sb掺杂对Mg2Si基热电材料的结构以及热电特性的影响.结果表明:通过Sb掺杂使得载流子浓度从3.07x1019 cm-3增加到1.25x1020 cm-3,电子有效质量也相应增加.测试了从室温到800 K下试样的Seebeck系数,电导率和热导率.结果显示,0.3 at%Sb掺杂使得电导率得到显著增加,在783 K时,ZT值达到0.7.
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| 关 键 词： | 热电 金属间化合物 掺杂 |
Effect of Sb-Doping on the Thermoelectric Properties of Mg_2Si Based Compounds |
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| Zhang Qian,Zhao Xinbing,Yin Hao,Zhu Tiejun.Effect of Sb-Doping on the Thermoelectric Properties of Mg_2Si Based Compounds[J].Rare Metal Materials and Engineering,2009,38(Z1). |
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| Authors: | Zhang Qian Zhao Xinbing Yin Hao Zhu Tiejun |
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| Affiliation: | Zhang Qian,Zhao Xinbing,Yin Hao,Zhu Tiejun (State Key Laboratory of Silicon Materials,Zhejiang University,Hangzhou 310027,China) |
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| Abstract: | Sb-doped and undoped Mg2Si thermoelectric materials were prepared by melting followed by hot-pressing. Effects of doped Sb on the structures and thermoelectric properties of the Mg2Si compounds were investigated. The carrier concentration increases from 3.07×1019 cm-3 to 1.25×1020 cm-3, and the electron effective mass increases by Sb doping. The Seebeck coefficient, the electrical conductivity and the thermal conductivity were measured from room temperature to 800 K,It is shown that the electrical conductivity increases dramatically due to the doping of 0.3 at% Sb, resulting in a higher dimensionless figure of merit of 0.7 at 783 K. |
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| Keywords: | thermoelectric intermetallic alloys and compounds doping |
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