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| 臭氧降解污染小麦中呕吐毒素的效果及降解产物推测 | |
| 引用本文： | 王 莉,罗颖鹏,罗小虎,王 韧,李永富,李亚男,邵慧丽,陈正行. 臭氧降解污染小麦中呕吐毒素的效果及降解产物推测[J]. 食品科学, 2016, 37(18): 164-170. DOI: 10.7506/spkx1002-6630-201618027 |
| 作者姓名： | 王 莉 罗颖鹏 罗小虎 王 韧 李永富 李亚男 邵慧丽 陈正行 |
| 作者单位： | 江南大学食品学院，粮食发酵工艺与技术国家工程实验室，食品科学与技术国家重点实验室，江苏 无锡 214122 |
| 基金项目： | 公益性行业（粮食）科研专项（201313005）；公益性行业（农业）科研专项（201203037）； 国家自然科学基金面上项目（31371874；31471616）；国家自然科学基金青年科学基金项目（31101383； 31201381；31501579）；江苏省博士后基金项目（1501078B）；国家国际科技合作专项（2015DFA30540） |
| 摘 要： | 利用臭氧降解小麦中的呕吐毒素，通过超高效液相色谱-串联四极杆飞行时间质谱（ultra performance liquidchromatography quadrupole time-of-flight mass spectrometry，UPLC Q-TOF MS）测定了纯水体系中呕吐毒素的臭氧降解产物。结果表明：全麦粉中的呕吐毒素降解率显著高于小麦籽粒。当小麦水分含量为20.10%，臭氧质量浓度为100 mg/L，处理60 min后，呕吐毒素含量由3.89 mg/kg 降到了0.83 mg/kg。建立的一级动力学方程显示臭氧反应速率为k100 mg/L＞k75 mg/L＞k50 mg/L＞k25 mg/L。根据UPLC Q-TOF MS得到离子碎片信息提出了可能的离子碎片生成途径并推测了臭氧降解产物结构，5 种主要产物的m/z分别为344.948 1、329.205 0、311.191 8、311.190 7和346.240 4。 |
| 关 键 词： | 小麦 呕吐毒素 臭氧 动力学 降解产物 |
Efficacy of Deoxynivalenol Detoxification by Ozone Treatment in Wheat and Prediction of Degradation Products |
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| WANG Li,LUO Yingpeng,LUO Xiaohu,WANG Ren,LI Yongfu,LI Yanan,SHAO Huili,CHEN Zhengxing. Efficacy of Deoxynivalenol Detoxification by Ozone Treatment in Wheat and Prediction of Degradation Products[J]. Food Science, 2016, 37(18): 164-170. DOI: 10.7506/spkx1002-6630-201618027 | |
| Authors: | WANG Li LUO Yingpeng LUO Xiaohu WANG Ren LI Yongfu LI Yanan SHAO Huili CHEN Zhengxing |
| Affiliation: | School of Food Science and Technology, National Engineering Laboratory for Cereal Fermentation Technology,State Key Laboratory of Food Science and Technology, Jiangnan University, Wuxi 214122, China |
| Abstract: | In this study, we used ozone to reduce deoxynivalenol (DON) in contaminated wheat, and the ozonation products were deduced using ultra performance liquid chromatography quadrupole time-of-flight mass spectrometry (UPLC Q-TOF MS). The results showed that DON content in whole wheat flour decreased more quickly than in wheat kernels. For wheat with a moisture content of 20.10%, DON content was reduced from 3.89 mg/kg to 0.83 mg/kg after 100 mg/L ozone treatment for 60 min. The kinetic model constants with different ozone concentrations showed the decreasing order of k100 mg/L＞k75 mg/L＞k50 mg/L＞k25 mg/L, which was consistent with the experimental results. According to the mass spectral and ion fragmentation information from UPLC Q-TOF, possible ozonation products were proposed. The m/z of the major products were 344.948 1, 329.205 0, 311.191 8, 311.190 7 and 346.240 4, respectively. |
| Keywords: | deoxynivalenol ozone kinetic degradation products |
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