| Keggin结构(C5H10NH2)4SiMo12O40的合成与表征 |
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| 引用本文： | 周端文.Keggin结构(C5H10NH2)4SiMo12O40的合成与表征[J].吉林化工学院学报,2007,24(2):1-2,8. |
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| 作者姓名： | 周端文 |
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| 作者单位： | 吉林化工学院,化学与制药工程学院,吉林,吉林,132022 |
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| 摘 要： | 用传统的方法合成了新型keggin结构电荷转移配合物(C5H10NH2)4SiMo12O40,并通过元素分析、紫外光谱及红外光谱对新合成的化合物进行表征.红外分析表明,多阴离子仍保持原来的Keggin骨架,其特征吸收峰有一定的红移或蓝移,说明哌啶与多阴离子之间有较强的相互作用.
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| 关 键 词： | 多金属氧酸盐 电荷转移配合物 Keggin结构 哌啶 |
| 文章编号： | 1007-2853（2007）02-0001-02 |
| 收稿时间： | 2007-01-05 |
| 修稿时间： | 2007-01-05 |
Synthesis and Characterization of Keggin Structure (C5H10NH2)4SiMo12O40 |
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| ZHOU Duan-wen.Synthesis and Characterization of Keggin Structure (C5H10NH2)4SiMo12O40[J].Journal of Jilin Institute of Chemical Technology,2007,24(2):1-2,8. |
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| Authors: | ZHOU Duan-wen |
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| Abstract: | A new charge-transfer hybrid of Keggin structure(C5H10NH2)4SiMo12O40 has been synthesized using conventional methods and characterized by elemental analyses,UV and IR spectrum.The IR analysis shows that the heterpolyanions still reserve their Keggin structure in this compound.Their absorptions have more or less blue shifts and red shift.It is the certificate of the strong interaction between the heterpolyanions and organic hybrids. |
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| Keywords: | polyoxometalate charge-transfer hybrid Keggin structure piperdine |
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