| 锆氢试剂与含硫有机化合物脱硫反应的研究 |
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| 引用本文： | 王梅,陆世维.锆氢试剂与含硫有机化合物脱硫反应的研究[J].化学试剂,1994,16(4):203-204,207. |
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| 作者姓名： | 王梅 陆世维 |
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| 作者单位： | 中国科学院大连化学物理研究所 |
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| 摘 要： | 锆氢试剂Ｃｐ２Ｚｒ（Ｈ）Ｃｌ，Ｃｐ２ＺｒＨ２可在温和条件下使直链或支链硫醇发生脱硫反应，生成相应的烷烃，使硫脲发生脱硫反应，生成氨和氢氰酸，并分别得到两种锆的硫桥络合物（Ｃｐ２ＺｒＣｌ）２Ｓ１和（Ｃｐ２ＺｒＳ）２ ２。而锆氢试剂与硫醚不能发生此类脱硫反应。
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| 关 键 词： | 锆氢试剂 含硫有机物 脱硫反应 |
Desulfurization reactions of zirconium hydride reagents with organic compounds containing sulfur |
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| Wang Mei, Lu Shiwei, Bei Meizhi, Cuo Hefu.Desulfurization reactions of zirconium hydride reagents with organic compounds containing sulfur[J].Chemical Reagents,1994,16(4):203-204,207. |
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| Authors: | Wang Mei Lu Shiwei Bei Meizhi Cuo Hefu |
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| Abstract: | Desulfurization reactions can occur between zirconium hydride reagents (Cp2Zr(H)Cl and Cp2ZrH2)and some organic compounds containing sulfur, such as straight- and branched-chain trio-alcohols to give corresponding alkanes, and thiourea to give ammonia and hydrocyanic acid. Two sulfur-bridged zirconocene complexes (Cp2ZrCl)2S 1 and (Cp2ZrS)2 2 were obtained from the reactions, respectively. By contrast,no reaction occurs between zirconium hydride reagents and trio-ethers. |
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| Keywords: | zirconium hydride reagent organic compounds containing sulfur desulfurization reaction |
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