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Correlation between glass transition temperature and melting temperature in metallic glasses
Affiliation:1. School of Mechanical, Electrical & Information Engineering, Shandong University (Weihai), Wenhua Xilu 180, 264209 Weihai, PR China;2. IFW Dresden, Institute for Complex Materials, Helmholtzstraße 20, D-01069 Dresden, Germany;3. IFW Dresden, Institute for Integrative Nanosciences, Helmholtzstraße 20, D-01069 Dresden, Germany;4. Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Jahnstraße 12, A-8700 Leoben, Austria;5. Department Materials Physics, Montanuniversität Leoben, Jahnstraße 12, A-8700 Leoben, Austria;1. Laboratoire LS3M, Faculté Polydisciplinaire de Khouribga, University Hassan 1, B.P. 145, 25000 Khouribga, Morocco;2. Laboratoire LS3M, Faculté Polydisciplinaire de Khouribga, University Sultan Moulay Slimane, B.P. 145, 25000 Khouribga, Morocco
Abstract:We report that the glass transition temperature (Tg) of a variety of metallic glasses (MGs) correlates with the eutectic or peritectic temperature of two main components corresponding stoichiometric proportion in their binary phase diagram. The correlation suggests that the Tg of MGs is mainly determined by their solvent of two base components, which have composition close to the eutectic and peritectic points in the binary phase diagram and the weakest link in amorphous structure. The results have implications for understanding the structure and glass transition in MGs and for predicting and designing metallic glasses with a desirable Tg.
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