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Preparation,characterization, and adsorption properties of chitosan microspheres crosslinked by formaldehyde for copper (II) from aqueous solution
Authors:Wen‐Li Du  Shan‐Shan Niu  Zi‐Rong Xu  Ying‐Lei Xu
Affiliation:1. Institute of Feed Science, College of Animal Science, Zhejiang University, The Key Laboratory of Molecular Animal Nutrition, Ministry of Education, Hangzhou 310029, China;2. Department of Horticulture, Zhejiang University, The State Agricultural Ministry Laboratory of Horticultural Plant Growth Development & Biotechnology, Hangzhou 310029, China
Abstract:The chitosan microspheres crosslinked by formaldehyde were prepared by spray drying method and used as an adsorbent for copper (II) from aqueous solution. A batch adsorption system was applied to study the adsorption of copper (II) from aqueous solution by chitosan microspheres. The maximum adsorption capacity of the chitosan microspheres for copper (II) was 144.928 mg/g at pH 6.0. Langmuir adsorption model was found to be applicable in interpreting the adsorption process. To elucidate the adsorption mechanism, the chitosan microspheres before and after copper (II) adsorption were further characterized by Fourier transform infrared spectra, zeta potential analysis, and scanning electron microscope. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009
Keywords:chitosan microspheres  spray drying  adsorption  copper (II)
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