Intrinsic Surface Dipoles Control the Energy Levels of Conjugated Polymers |
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Authors: | Georg Heimel Ingo Salzmann Steffen Duhm Jürgen P Rabe Norbert Koch |
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Affiliation: | 1. Institut für Physik Humboldt‐Universit?t zu Berlin Newtonstr. 15 Berlin, 12489 (Germany);2. Graduate School of Advanced Integration Science Chiba University 1‐33 Yayoi‐cho, Inage‐ku Chiba 263‐8522 (Japan) |
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Abstract: | Conjugated polymers are an important class of materials for organic electronics applications. There, the relative alignment of the electronic energy levels at ubiquitous organic/(in)organic interfaces is known to crucially impact device performance. On the prototypical example of poly(3‐hexylthiophene) and a fluorinated derivative, the energies of the ionization and affinity levels of π‐conjugated polymers are revealed to critically depend on the orientation of the polymer backbones with respect to such interfaces. Based on extensive first‐principles calculations, an intuitive electrostatic model is developed that quantitatively traces these observations back to intrinsic intramolecular surface dipoles arising from the π‐electron system and intramolecular polar bonds. The results shed new light on the working principles of organic electronic devices and suggest novel strategies for materials design. |
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Keywords: | Conjugated polymers Organic electronics Structure– property relationships Thin films |
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