High‐Pressure Synthesis of Tantalum Nitride Having Orthorhombic U2S3 Structure |
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Authors: | Andreas Zerr Gerhard Miehe Jinwang Li Dmytro A Dzivenko Vadim K Bulatov Heidi Höfer Nathalie Bolfan‐Casanova Michel Fialin Gerhard Brey Tomoaki Watanabe Masahiro Yoshimura |
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Affiliation: | 1. LPMTM‐CNRS, Université Paris Nord 99 av. J. B. Clement, 93430 Villetaneuse (France);2. FB Material‐ und Geowissenschaften Technische Universit?t Darmstadt Petersenstrasse 23, 64287 Darmstadt (Germany);3. Materials and Structures Laboratory Tokyo Institute of Technology 4259‐R3‐20 Nagatsuta, Midori‐ku, Yokohama 226‐8503 (Japan);4. Institut für Geowissenschaften Goethe‐Universit?t 60438 Frankfurt am Main (Germany);5. LMV‐CNRS, Université Clermont Ferrand 5 rue Kessler, 63038 Clermont Ferrand (France);6. Centre de microanalyse CAMPARIS‐CNRS‐UMR7154 Institut de Physique du Globe de Paris 4 place Jussieu, BP 89, 75252 Paris Cedex 05 (France) |
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Abstract: | Among binary compounds, there is a high potential for discovery of novel members (polymorphic phases or compounds) of the nitrides of transition metals group due to a pronounced dependence of the oxidation state of the metals (M) on pressure. The power of high pressure–high temperature (HP‐HT) route for synthesis of binary nitrides has already been demonstrated by the discovery of cubic nitrides of the group 4 and 14 elements, of crystalline polymorphs of P3N5, and by reports on formation of four noble metal nitrides. It is anticipated that such HP products exhibit, in addition to enhanced elastic and mechanical behavior, other functional properties making them interesting for industrial applications. Here, HP–HT synthesis research is extended to nitrides of group 5 elements, resulting in the discovery of a novel hard tantalum nitride, exhibiting U2S3 structure: η‐Ta2N3 (Pbnm, a = 8.1911(17) Å, b = 8.1830(17) Å, c = 2.9823(3) Å). The stoichiometry is supported by two independent means, verifying that η‐Ta2N3 is the first thermodynamically stable transition metal nitride with a N:M ratio exceeding 4:3. Due to its high hardness and peculiar texture (needle‐like and granular crystallites), η‐Ta2N3 may find practical applications as a hard fracture resistant material. |
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Keywords: | ceramics high‐pressure synthesis tantalum nitrides |
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