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Selective Electrochemical Etching of Single‐Walled Carbon Nanotubes
Authors:Dacheng Wei  Yunqi Liu  Lingchao Cao  Hongliang Zhang  Liping Huang  Gui Yu  Hisashi Kajiura  Yongming Li
Affiliation:1. Beijing National Laboratory for Molecular Sciences Organic Solids Laboratory Institute of Chemistry Chinese Academy of Sciences Beijing 100 190 (PR China);2. Material Laboratory Sony Corporation Kanagawa 243‐0021 (Japan)
Abstract:Single‐walled carbon nanotubes (SWNTs) are a promising material for future nanotechnology. However, their applications are still limited in success because of the co‐existence of metallic SWNTs and semiconducting SWNTs produced samples. Here, electrochemical etching, which shows both diameter and electrical selectivity, is demonstrated to remove SWNTs. With the aid of a back‐gate electric field, selective removal of metallic SWNTs is realized, resulting in high‐performance SWNT field‐effect transistors with pure semiconducting SWNT channels. Moreover, electrochemical etching is realized on a selective area. These findings would be valuable for research and the application of SWNTs in electrochemistry and in electronic devices.
Keywords:Single‐walled carbon nanotubes  Multiwalled carbon nanotubes  Electrodes  Field‐effect transistors
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