| O/W型微乳液应用于三线态湮灭上转换介质研究 |
| |
| 引用本文： | 郝荣康,徐伟建,陈晓,叶常青,孙彬,丁平,王宝,王筱梅.O/W型微乳液应用于三线态湮灭上转换介质研究[J].信息记录材料,2014,15(6):21-26. |
| |
| 作者姓名： | 郝荣康 徐伟建 陈晓 叶常青 孙彬 丁平 王宝 王筱梅 |
| |
| 作者单位： | 苏州科技学院化学生物与材料工程学院环境功能材料省重点实验室 苏州215009 |
| |
| 基金项目： | 江苏省自然科学基金，江苏省环境功能材料重点实验室开放基金资助，苏州市应用基础研究计划 |
| |
| 摘 要： | 光子上转换是吸收低能量（长波长）的光发射高能量（短波长）光的过程,在太阳能光伏、光催化等领域具有潜在应用价值而受到广泛研究,然而通常介质采用有机溶剂及绝氧处理都大大限制了上转换的实际应用.本文报道了可用于三线态湮灭上转换过程的新介质-O/W型微乳液,该体系制备简单、无毒环保,无需除氧脱气条件下,上转化发光稳定,具有未来实际应用的潜力.
|
| 关 键 词： | 弱光 上转换 三线态-三线态湮灭 微乳液 |
Oil/water Microemulsion Applied as an Effective Medium for Triplet Triplet Annihilated Upconversion |
| |
| HAO Rong-kang;YE Chang-qing;DING Ping;SUN Bin;WANG Bao;WANG Xiao-mei.Oil/water Microemulsion Applied as an Effective Medium for Triplet Triplet Annihilated Upconversion[J].Information Recording Materials,2014,15(6):21-26. |
| |
| Authors: | HAO Rong-kang;YE Chang-qing;DING Ping;SUN Bin;WANG Bao;WANG Xiao-mei |
| |
| Affiliation: | HAO Rong-kang;YE Chang-qing;DING Ping;SUN Bin;WANG Bao;WANG Xiao-mei;School of Chemistry, Biology and Materials Engineering, Jiangsu Key Laboratory of Environmenalt Functional Materials, Suzhou University of Science and Technology; |
| |
| Abstract: | The triplet-triplet annihilated upconversion （TTA-UC） is one of hotspot researches on the pho- ton-upconversion mechanism, due to TTA-UC can be obtained at low excitation intensity and would bring about many practical applications such as photovoltaics and photocatalysis. However, the application of TTA-UC is facing the limitation because it relies exclusively on the efficient generation of the triplet excited states of both sensitizer and acceptor. Dissolved 02 can strongly annihilate these formed triplets. So the conventional organic solvent served as the upconversion medium must he devoid of oxygen to prevent triplet-state quenching, which is absolutely not ideal for the most TTA-UC applications. In this paper, we reported a new medium for triplet-triplet annihilated upconversion, that is, the oil-in-water （o/w） microemulsion without degassing any more. There is no need for the upconverted o/w microemulsion to deaerate, which is of critical importance for the TTA-UC application |
| |
| Keywords: | low-power upconversion triplet-triplet annihilated microemulsion |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
