| 环氧SBS开环制备顺酐化离聚体及其物化性能的研究 |
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| 引用本文： | 喻武钢,谢洪泉. 环氧SBS开环制备顺酐化离聚体及其物化性能的研究[J]. 弹性体, 2006, 16(3): 32-36 |
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| 作者姓名： | 喻武钢 谢洪泉 |
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| 作者单位： | 1. 湖北省化学研究院,湖北,武汉,430074
2. 华中科技大学,化学系,湖北,武汉,430074 |
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| 摘 要： | 利用环氧化苯乙烯-丁二烯-苯乙烯嵌段共聚物（ESBS）的环氧基与顺丁烯二酸氢钾（HKM）在相转移催化剂和开环催化剂存在的条件下开环反应制得钾离聚体。研究了其反应条件，由于添加了助剂BM，环氧基开环率达到了95．2％，并用FTIR确定了离聚体的生成；通过对不同环氧值ESBS开环反应，研究了不同离子基团质量摩尔浓度对离聚体物化性能的影响。
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| 关 键 词： | 离聚体 环氧化SBS 顺酐化 开环反应 热塑性弹性体 |
| 文章编号： | 1005-3174（2006）03-0032-05 |
| 收稿时间： | 2005-12-25 |
| 修稿时间： | 2005-12-25 |
Preparation characterization and properties of SBS ionomers via ring-opening reaction of epoxidized SBS with potassium hydrogen maleate |
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| YU Wu-gang,XIE Hong-quan. Preparation characterization and properties of SBS ionomers via ring-opening reaction of epoxidized SBS with potassium hydrogen maleate[J]. China Elastomerics, 2006, 16(3): 32-36 |
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| Authors: | YU Wu-gang XIE Hong-quan |
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| Affiliation: | 1. Hubei Research Institute of Chemistry, Wuhan 430074, China ; 2. Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China |
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| Abstract: | Epoxidized styrene-butadiene-styrene triblock copolymer(ESBS) can react with potassium hydrogen maleate by ring-opening reaction in the presence of phase transfer catalyst and ring-opening catalyst.Epoxy conversion reached to 95.2% in the existence of a basic accelerator.The purified product was characterized by FTIR spectrum.Emulsifying properties,water and oil absorbency as well as dilute solution viscosity were studied. |
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| Keywords: | ionomers epoxy SBS maleation ring-opening reaction thermoplastic elastomer |
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