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Electrospinning of thermo-regulating ultrafine fibers based on polyethylene glycol/cellulose acetate composite
Authors:Changzhong Chen  Linge Wang  Yong Huang
Affiliation:a Key Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, China
b Graduate School of Chinese Academy of Sciences, Beijing 100049, China
c State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
Abstract:Ultrafine fibers of polyethylene glycol/cellulose acetate (PEG/CA) composite in which PEG acts as a model phase change material (PCM) and CA acts as a matrix, were successfully prepared as thermo-regulating fibers via electrospinning. The morphology observation from the electrospun PEG/CA composite fibers revealed that the fibers were cylindrical and had a smooth external surface. PEG was found to be both distributed on the surface and within the core of the fibers. Differential scanning calorimeter (DSC) was used to characterize the thermal properties of the composite fibers. The results indicated that the fibers imparted balanced thermal storage and release properties for their thermo-regulating function and the thermal properties were reproducible after 100 heating-cooling cycles.
Keywords:Electrospinning   Phase change material   Thermo-regulating fibers
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