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Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening
Authors:Lucjan Chmielarz  Roman Dziembaj  Teresa Grzybek  Jerzy Klinik  Tomasz Łojewski  Danuta Olszewska  Helmut Papp
Affiliation:(1) Faculty of Chemistry, Jagellonian University, 30-059 Krakow, Poland;(2) Faculty of Fuels and Energy, University of Mining and Metallurgy, 30-059 Krakow, Poland;(3) Lehrstuhl für Technische Chemie, Faculty of Chemistry and Mineralogy, Leipzig University, 04103 Leipzig, Germany
Abstract:Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pretreated smectites were used. The acid pretreatment increased NO conversion and influenced the extent of carbon introduction into the porous system. The carbon deposit improved selectivity of the catalytic reduction to N2. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:SCR  texture  XRD  smectites  carbon deposits
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