| 海砂砂浆碳化过程的电化学阻抗谱研究 |
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| 引用本文： | 施微丹,吴应雄. 海砂砂浆碳化过程的电化学阻抗谱研究[J]. 建筑材料学报, 2018, 21(4): 645-649 |
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| 作者姓名： | 施微丹 吴应雄 |
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| 作者单位： | 福州理工学院工学院;福州大学土木工程学院 |
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| 基金项目： | 国家自然科学基金资助项目（51778149）；福建省教育厅中青年教师教育科研项目（JAT170790） |
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| 摘 要： | 通过建立新的电化学等效电路模型,分析了海砂砂浆的碳化行为,并对新模型进行理论数学推导,得出了新模型在复平面中的曲线方程;同时通过对比分析验证了新模型的合理性.结果表明:碳化过程会引起海砂砂浆的电化学阻抗谱行为发生规律性的变化,高频圆直径随碳化龄期增大而增大;由电化学阻抗谱拟合获得的电化学模型参数具有规律性,可以定量表征海砂砂浆的碳化过程,其参数分别与碳化深度和碳化时间存在函数关系,可以对海砂砂浆的碳化深度进行预测.
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| 关 键 词： | 海砂砂浆； 电化学阻抗谱； 等效电路模型； 预测； 碳化深度 |
| 收稿时间： | 2017-09-12 |
| 修稿时间： | 2017-12-01 |
Electrochemical Impedance Spectroscopy of the Carbonation Behavior of Mortar with Marine Sand |
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| SHI Weidan and WU Yingxiong. Electrochemical Impedance Spectroscopy of the Carbonation Behavior of Mortar with Marine Sand[J]. Journal of Building Materials, 2018, 21(4): 645-649 |
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| Authors: | SHI Weidan and WU Yingxiong |
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| Affiliation: | College of Engineering, Fuzhou Institute of Technology, Fuzhou 350506, China and College of Civil Engineering, Fuzhou University, Fuzhou 350116, China |
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| Abstract: | A new electrochemical model has been established to explain the carbonation behavior of marine sand mortars. To conduct the mathematical derivation of the new model, a curvilinear equation in Nyquist plot was acquired. The reliability of the model has been proved by way of comparing the new model with the previous. The experimental results demonstrate that electrochemical impedance behavior of mortars has been moderated in the process of the carbonation. The carbonation process can be quantitatively analyzed by the parameters fitted from the electrochemical model. Moreover, prediction of the carbonation depth can be achieved. |
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| Keywords: | marine sand mortar electrochemical impedance spectrum equivalent circuit model prediction carbonation depth |
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