| 打造我国主体能源(煤炭)升级版面临的主要问题与对策探讨 |
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| 引用本文： | 季燕男, 张雷林, 陈朝卫. 复合阻化剂抑制煤燃烧特性实验研究[J]. 矿业安全与环保, 2023, 50(4): 25-29. DOI: 10.19835/j.issn.1008-4495.2023.04.005 |
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| 作者姓名： | 季燕男 张雷林 陈朝卫 |
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| 作者单位： | 1.安徽理工大学 安全科学与工程学院，安徽 淮南 232001;2.安徽理工大学 煤炭高效开采省部共建教育部重点实验室，安徽 淮南 232001;3.郑煤集团裴沟煤矿筛选厂，河南 郑州 452382 |
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| 基金项目： | 国家自然科学基金项目(51874008) |
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| 摘 要： | 为了研究阻化剂对煤燃烧特性的影响，选取柠檬酸钠和聚磷酸铵进行复配，开展复合阻化剂优选的实验研究。采用锥形量热仪在45 kW/m2的热辐射强度下, 分析阻化煤样的燃烧行为和阻化效果。结果表明，在选取的实验比例中，当柠檬酸钠与聚磷酸铵的质量比为3∶1时，煤燃烧的热释放速率和总热释放量明显降低，烟气持续生成时间有效缩短，抑制了烟气的产生，体现出优良的阻燃抑烟效果；在煤炭的燃烧效率方面，提高了体系的火灾性能指数，降低了火灾增长指数，有效抑制了煤炭的燃烧，表现出复合阻化剂良好的协效作用。
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| 关 键 词： | 煤 燃烧特性 复合阻化剂 聚磷酸铵 柠檬酸钠 阻燃性能 锥形量热仪 |
| 收稿时间： | 2022-05-18 |
| 修稿时间： | 2022-08-20 |
A study on the modification of polypropylene by a star-shaped intumescent flame retardant containing phosphorus and nitrogen |
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| JI Yannan, ZHANG Leilin, CHEN Chaowei. Experimental study on combustion inhibition characteristics of coal with compound inhibitor[J]. Mining Safety & Environmental Protection, 2023, 50(4): 25-29. DOI: 10.19835/j.issn.1008-4495.2023.04.005 |
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| Authors: | JI Yannan ZHANG Leilin CHEN Chaowei |
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| Affiliation: | 1.School of Safety Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China;2.Key Laboratory of Coal Efficient Mining, Ministry of Education, Anhui University of Science and Technology, Huainan 232001, China;3.Sizing Plant of Peigou Coal Mine, Zhengzhou Coal Industry(Group) Co., Ltd., Zhengzhou 452382, China |
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| Abstract: | In order to study the effect of the inhibitor on the combustion characteristics of coal, sodium citrate and ammonium polyphosphate were mixed to carry out the experimental study on the optimization of the compound inhibitor. The combustion behavior and blocking effect of the retarded coal sample were analyzed with a cone calorimeter at the thermal radiation intensity of 45 kW/m2. The results show that among the selected experimental ratios, when the mass ratio of sodium citrate to ammonium polyphosphate is 3∶1, the heat release rate and total heat release of coal combustion are significantly reduced, the smoke generation duration is effectively shortened, and the smoke generation is inhibited, reflecting excellent flame retardant and smoke suppression effects. In the combustion efficiency of coal, the fire performance index of the system is improved, and the fire growth index is reduced. The combustion of coal is effectively inhibited, showing a good synergistic effect of the compound inhibitor. |
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| Keywords: | coal combustion characteristic compound inhibitor ammonium polyphosphate sodium citrate flame retardant property cone calorimeter |
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