Phosphate triester hydrolysis promoted by S3–zinc(II) complexes with a bridged hydroxide: The crystal structure of TtiZn–OP(O)(OC6H4-p-NO2)2, Tti = hydrotris(N-xylyl-2-thioimidazolyl)borate |
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| Authors: | Mohamed M Ibrahim |
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| Affiliation: | aChemistry Department, Faculty of Education, Tanta University, Kafr-Elsheikh Branch, P.O. Box 33516, Egypt |
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| Abstract: | The bridged μ-hydroxo dinuclear four-co-ordinated zinc(II) complex 2, derived from hydrotris(N-xylyl-2-thioimidazolyl)borate cleaves the P–O bond in tris(p-nitrophenyl)phosphate to form a mixture of a monomeric phosphate diester complex 3 and phenoxo complex 4. |
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| Keywords: | S3– zinc(II) complexes Crystal structure Phosphate ester Hydrolysis |
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