|
|||||
|
|
High catalytic activity for synthesis of aniline from phenol and ammonia found on gallium-containing MFI |
|
| Authors: | Naonobu Katada Shuji Kuroda Miki Niwa |
| Affiliation: | Department of Materials Science, Faculty of Engineering, Tottori University, 4-101, Koyama-cho Minami Tottori 680-8552 Japan |
| Abstract: | Gallium-containing zeolitic materials, i.e., MFI-type gallosilicate and gallium-loaded ZSM-5 zeolite, exhibited quite high activity for vapor-phase reaction of phenol and ammonia into aniline. Co-presence of the extra-framework gallium species and the ion-exchange site ascribed to framework gallium or aluminum atom is considered to generate the high activity. |
| Keywords: | Aniline Phenol Ammonia Gallosilicate Gallium-loaded ZSM-5 Extra-framework gallium Solid–acid catalysis |
| 本文献已被 ScienceDirect 等数据库收录！ | |