Electrochemical evaluation of double perovskite PrBaCo2-xMnxO5+δ (x = 0, 0.5, 1) as promising cathodes for IT-SOFCs |
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| Authors: | Xiubing Huang Jie Feng Hassan RS Abdellatif Jing Zou Guan Zhang Chengsheng Ni |
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| Affiliation: | 1. Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China;2. Beijing Key Laboratory for Chemical Power Source and Green Catalysis, School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China;3. College of Resources and Environment, Southwest University, Chongqing 400716, China;4. School of Humanities & Social Science, The Chinese University of Hong Kong, Shenzhen, Shenzhen 518100, China;5. Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution Control, School of Civil and Environmental Engineering, Harbin Institute of Technology, Shenzhen, Shenzhen, 518055, China |
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| Abstract: | Mn-substituted double perovskites, PrBaCo2-xMnxO5+δ (x = 0, 0.5, 1), are evaluated as cathode materials for intermediate-temperature solid oxide fuel cells. The effects of Mn substitution content on their structural and electrochemical properties including crystal structure, thermal expansion coefficient, and cathodic interfacial polarization resistance are investigated. The PrBaCo2-xMnxO5+δ samples exhibit structural changes with increasing Mn contents from tetragonal (x = 0) to cubic (x = 0.5 and 1.0) symmetry. The thermal expansion coefficient decreases with the increasing Mn content while the cathodic performance increases with the increment of Mn content from x = 0 to x = 0.5 then decreases with the further increment of Mn content from x = 0.5 to x = 1.0. When using La0.8Sr0.2Ga0.8Mg0.15Co0.05O3 with 300 μm thickness as electrolyte and Sr2Fe1.4Ni0.1Mo0.5O6-δ as anode, the maximum powder density of the x = 0.5 composite is 0.638 W cm?2, which is higher than that of the other two samples with x = 0 (0.474 W cm?2) and x = 1.0 (0.371 W cm?2) at 800 °C. |
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| Keywords: | Solid oxide fuel cells Cathode Double perovskite Doping |
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