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Transport of Organic Contaminants in Geomembranes under Stress
Authors:S. Xiao  C. Moresoli  A. Burczyk  P. Pintauro  D. De Kee
Affiliation:11Production Mgr., Oricolor Inc., 12180 Industrical Blvd., Montreal, PQ, Canada H1B 5R7.
22Assoc. Prof., Dept. of Chemical Engrg., Univ. of Waterloo, Waterloo, ON, Canada H2L 3G1.
33Sci., Defence Res. Establishment Suffield, Box 4000, Medicine Hat, AB, Canada T1A 8K6.
44Prof., Dept. of Chemical Engrg., Tulane Univ., New Orleans, LA 70118-5674.
55Prof., Dept. of Chemical Engrg., Tulane Univ., New Orleans, LA; corresponding author.
Abstract:The transport properties of aqueous solutions of benzene, dichloromethane, and trichloroethylene through extended polyvinyl chloride and high-density polyethylene geomembranes are investigated. It is found that extension enhances the permeation rates of the penetrants through polyvinyl chloride geomembranes, and the opposite effect is found in the case of high-density polyethylene. This difference in response is attributed to the type of structural change, which occurred as a result of the extension. The diffusivities of a mixture of the three organic solvents through the geomembranes are also determined.
Keywords:
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