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D-呋喃木糖酯类化合物的合成及其在单料烟中的应用
引用本文:刘乐,赵铭钦,姬小明,刘云,张晓蕴.D-呋喃木糖酯类化合物的合成及其在单料烟中的应用[J].香料香精化妆品,2011(4):11-16.
作者姓名:刘乐  赵铭钦  姬小明  刘云  张晓蕴
作者单位:1. 河南农业大学烟草学院,郑州,450002
2. 宝鸡市烟草公司,宝鸡,721000
基金项目:河南省教育厅自然科学研究资助计划项目(2010B150010); 国家烟草专卖局重大科技攻关项目(110200401014)
摘    要:利用二环己基碳二亚胺(DCC)作缩水剂,4-二甲氨基吡啶(DMAP)为催化剂,以1,2-O-异丙叉基-α-D-呋喃木糖和11种酸为原料,合成了11种具有潜在香味的木糖酯类化合物,结构经1H-NMR、13C-NMR、IR和HRMS图谱检测得到验证,并进行了卷烟加香试验.评吸结果表明,合成的该系列化合物可以提高卷烟烟气的香...

关 键 词:呋喃木糖酯类  潜香化合物  卷烟加香

Synthesis of D-xylofuranoses and their Application in Cigarette
LIU Le,ZHAO Mingqin,JI Xiaoming,LIU Yun,ZHANG Xiaoyun.Synthesis of D-xylofuranoses and their Application in Cigarette[J].Flavour Fragrance Cosmetics,2011(4):11-16.
Authors:LIU Le  ZHAO Mingqin  JI Xiaoming  LIU Yun  ZHANG Xiaoyun
Affiliation:LIU Le1 ZHAO Mingqin1 JI Xiaoming1 LIU Yun2 ZHANG Xiaoyun1(1.College of Tobacco Science,Henan Agricultural University,Zhengzhou 450002,China,2.Tobacco Company of Baoji City,Baoji 721000,China)
Abstract:With 4-dimethylamionpyridine (DMAP) as catalyst and dicyclohexylcarbodiimide (DCC) as dehydration reagent, 11 kinds of compounds with potential flavor were synthesized from 1,2-O-propylidene-a-D-xylofuranose and 11 kinds of acids. The profiles of compounds were confirmed by 1 H-NMR,13C-NMR.IR and HRMS spectra, and applied into cigarettes as a flavor. The results showed that the synthesized products had the functions of enhancing aroma quality and cigarette smoke, reducing irritancy and improving aftertaste.
Keywords:D-xylofuranoses compounds with potential flavor cigarette flavoring  
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