| 人工气候老化对乙丙橡胶表面结构的影响 |
| |
| 引用本文： | 徐业彬 王典芬. 人工气候老化对乙丙橡胶表面结构的影响[J]. 高分子材料科学与工程, 1995, 11(6): 144-148 |
| |
| 作者姓名： | 徐业彬 王典芬 |
| |
| 作者单位： | 华中理工大学固电系，武汉工业大学 |
| |
| 摘 要： | 乙丙橡胶在户外绝缘系统中应用广泛，其性质和表面结构在环境因素作用下会发生变化。应用ＳＥＭ、ＸＰＳ等技术研究了加速气候老人经对乙丙橡胶表面结构的影响。老化后橡胶表面出现微裂纹，链端氧化或链的断裂导致ＣＯＯ－出现。随老化时间增加，高氧化态碳（ＣＯＯ－）相对含量增加，Ｏ／Ｃ增加，ＯＩＳ平均结构能降低。
|
| 关 键 词： | 乙丙橡胶 气候 老化 橡胶 高聚物 表面结构 |
EFFECT OF ACCELERATED WEATHER AGING ON THE SURFACE STRUCTURE OF EPDM RUBBER |
| |
| Xu Yebing,Zeng Fandi, Li Xingjiao. EFFECT OF ACCELERATED WEATHER AGING ON THE SURFACE STRUCTURE OF EPDM RUBBER[J]. Polymer Materials Science & Engineering, 1995, 11(6): 144-148 |
| |
| Authors: | Xu Yebing Zeng Fandi Li Xingjiao |
| |
| Abstract: | EPDM rubber was widely used in outdoor insulation systems.Its properties and surface structure were affected by enviromental stresses during service.Through accelerated weather aging, surface structural changes of EPDM rubber were investigated by XPS and SEM techniques in this paper.The results show that there are a net of fine cracks on the surface of aged EPDM rubber.With increasing aging time,O/C atomic ratio and the relative quantity of C atoms in higher oxidation states(COO )increase. O1s average binding energy decreases.The aging mechanism is also discussed. |
| |
| Keywords: | s: EPDM rubber outdoor insulation weathering XPS technique |
| 本文献已被 CNKI 维普 等数据库收录！ |
