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早强型聚羧酸系高性能减水剂合成研究
引用本文:郭春芳,张明. 早强型聚羧酸系高性能减水剂合成研究[J]. 新型建筑材料, 2012, 0(4): 45-47
作者姓名:郭春芳  张明
作者单位:1. 山东丝绸纺织职业学院,山东淄博,255300
2. 山东华伟银凯建材科技股份有限公司,山东淄博,256410
摘    要:聚羧酸系减水剂早期强度发展缓慢的问题限制了其应用.研究了以不同分子质量的大单体甲氧基聚乙二醇丙烯酸酯(MPEGA)、(甲基)丙烯酸和消泡单体合成早强型聚羧酸系高性能减水剂,确定了合成产品的最佳工艺条件为:n(MPEGA4000):n(丙烯酸):n(消泡单体)=1.0:4.0:0.2,中和剂为二乙醇胺.与市场上同类产品相比,合成的产品具有较高的早期强度,接近国外同类产品的性能.

关 键 词:聚羧酸系减水剂  早期强度  消泡单体  中和剂

Research on synthesis of a high early strength polycarboxylate superplasticizer
GUO Chunfang , ZHANG Ming. Research on synthesis of a high early strength polycarboxylate superplasticizer[J]. New Building Materials, 2012, 0(4): 45-47
Authors:GUO Chunfang    ZHANG Ming
Affiliation:1.Shandong Silk Textile Vocational College,Zibo 255300,Shandong,China; 2.Shandong Huawei Yinkai Building Materials Science and Technology Stock Co.Ltd.,Zibo 256410,Shandong,China)
Abstract:The application of the polycarboxylate superplasticizer was restricted because of its low early strength.A high early strength polycarboxylate superplasticizer was synthesized by different molecular macromonomer MPEGA,(M)AA and a defoaming monomer.The experiment results showed that the copolymer had an excellent property when the molar ratio of MPEGA4000,AA and defoaming monomer was 1.0∶4.0∶0.2,which the neutralization agent was diethanolamine.Compared with the like product in the market,the copolymer had an higher early strength,achieving the performance of foreign product.
Keywords:polycarboxylate superplasticizer  early strength  defoaming monomer  neutralization agent
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