Synthesis and properties of methyl hexahydrophthalic anhydride‐cured fluorinated epoxy resin 2,2‐bisphenol hexafluoropropane diglycidyl ether |
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| Authors: | Miao Yin Li Yang Xiu‐yun Li Han‐bing Ma |
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| Affiliation: | 1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, , Mianyang, People's Republic of China;2. National Engineering Technology Center for Insulation Materials, Southwest University of Science and Technology, , Mianyang, People's Republic of China |
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| Abstract: | The fluorinated epoxy resin, 2,2‐bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two‐step procedure, and the chemical structure was confirmed by 1H n uclear magnetic resonance (NMR), 13C NMR, and Fourier transform infrared (FTIR) spectra. Moreover, DGEBHF was thermally cured with methyl hexahydrophthalic anhydride (MHHPA). The results clearly indicated that the cured DGEBHF/MHHPA exhibited higher glass transition temperature (Tg 147°C) and thermal decomposition temperature at 5% weight loss (T5 372°C) than those (Tg 131.2°C; T5 362°C) of diglycidyl ether of bisphenol A (DGEBA)/MHHPA. In addition, the incorporation of bis‐trifluoromethyl groups led to enhanced dielectric properties with lower dielectric constant (Dk 2.93) of DGEBHF/MHHPA compared with cured DGEBA resins (Dk 3.25). The cured fluorinated epoxy resin also gave lower water absorption measured in two methods relative to its nonfluorinated counterparts. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2801–2808, 2013 |
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| Keywords: | thermosets synthesis and processing dielectric properties thermal properties structure‐property relations |
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