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Conductive composites of PVC and wood's metal with interpenetrating network structure
Authors:Monika Trojanowska‐Tomczak  Ryszard Steller  Jarosław Janukiewicz  Jan Ziaja  Grzegorz Szafran
Affiliation:1. Polymer Engineering and Technology Department, Wroc?aw University of Technology, Wybrze?e Wyspiańskiego 27, 50‐370 Wroc?aw, Poland;2. Institute of Telecommunication, Radiocommunication and Teleinformatics Department, Teleinformatics and Acoustics, Wroc?aw University of Technology, Wybrze?e Wyspiańskiego 27, 50‐370 Wroc?aw, Poland;3. Institute of Electrical Engineering Fundamentals, Electrotechnology Department, Wroc?aw University of Technology, Wybrze?e Wyspiańskiego 27, 50‐370 Wroc?aw, Poland
Abstract:This work presents composite materials with interpenetrating network structure based on thermoplastic polymer and low melting metal alloy. Composites with various alloy content were prepared by PVC powder sintering to obtain polymer matrix with open pores. Then, liquid Wood's metal was intruded into the matrix using a pressure autoclave. Obtained composites have been studied with respect to microstructure, mechanical, thermal, and electrical properties. SEM micrographs revealed good dispersion of metal in the matrix but at low loading levels it is incomplete. Addition of metal improved mechanical properties, especially flexural strength. Electrical resistivity of samples varies from 10?4 to 10?5 Ω m and these values are typical of conductors. The measurements of electromagnetic interference shielding effectiveness (EMI SE) shows that generally PVC/Wood's metal composites have a good ability to shield electromagnetic waves. Composites containing more than 15 vol % Wood's metal exhibited EMI SE above 40 dB in the major part of frequency range. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
Keywords:composites  mechanical properties  morphology  poly(vinyl chloride)  porous materials
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