The effect of twin screw extrusion on structural,electrical, and rheological properties in carbon nanotube poly‐ether‐ether‐ketone nanocomposites |
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| Authors: | Matthieu Guehenec Victoria Tishkova Sylvie Dagreou Frederic Leonardi Christophe Derail Pascal Puech François Pons Benedicte Gauthier Pierre‐Henri Cadaux Wolfgang Bacsa |
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| Affiliation: | 1. Université de Pau et des Pays de l'Adour, IPREM, Equipe de Physique et Chimie des Polymères‐UMR CNRS/UPPA 5254, Technopole Helioparc, 2, av. Pdt Angot, 64053 Pau Cedex 9, France;2. CEMES/CNRS, 29 Jeanne Marvig, Université de Toulouse, 31055 Toulouse, France;3. AIRBUS FRANCE (B.E. M&P Toulouse), 316 Route de Bayonne, 31060 Toulouse, France |
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| Abstract: | The influence of twin screw extruder dispersion of multiwalled carbon nanotubes (CNTs) on the structural, electrical, and rheological properties in poly(ether ether ketone) is studied. Intermediate rotational speeds (200 rpm) of co‐rotating twin screws yield higher electrical conductivity and dynamic shear modulus than for lower or higher speeds when using 3 wt % multiwall CNTs. These improved properties at intermediate speeds are correlated with the dispersion state of nanotubes in the polymer matrix by using transmission electron microscopy and multispectral Raman mapping. We find that the complex shear modulus near structural percolation depends on the dispersion of the CNTs and the residence time in the extruder plays an important role in the final properties of the nanocomposite. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
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| Keywords: | composites nanotubes rheology spectroscopy |
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