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Synergistic effect of organo‐montmorillonite on intumescent flame retardant ethylene‐octene copolymer
Authors:Jianbing Guo  Min He  Qingfeng Li  Jie Yu  Shuhao Qin
Affiliation:1. Division of technology R&D, National Engineering Research Center for Compounding and Modification of Polymer Materials, Guizhou, Guiyang 550014, China;2. Research and Development Department (R&D), Guizhou Kumkuat Materials CO., LTD, Guizhou, Guiyang 550014, China
Abstract:Nanocomposite of thermoplastic elastomer ethylene‐octene copolymer/maleated ethylene‐octene (POE/POE‐g‐MAH) with organo‐montmorillonite (OMMT, 11 wt %) as masterbatch have been obtained by melt blending and it has been characterized by transmission electron microscopy (TEM). Flame retardant POE/POE‐g‐MAH/OMMT/ammonium polyphosphate‐pentaerythritol (APP‐PER) (an intumescent flame retardant with 75 wt % ammonium polyphosphate and 25 wt % pentaerythritol) composites were prepared by using melting processing to study their structures, flame‐retardancy, thermal, and mechanical properties. TEM showed exfoliated structures throughout POE/POE‐g‐MAH/OMMT masterbatch and POE/POE‐g‐MAH/OMMT/APP‐PER nanocomposites. Synergistic effect was observed between OMMT and APP‐PER resulting in significant improvements on thermal stability, flame‐retardancy and mechanical properties in the POE/POE‐g‐MAH/OMMT/APP‐PER nanocomposites. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
Keywords:clay  elastomer  flame retardant  thermal properties  mechanical properties
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