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Exfoliated polymer nanocomposites by in situ coprecipitation of layered double hydroxides in a polymer matrix
Authors:Julien Gaume  Sandrine Therias  Fabrice Leroux  Agnès Rivaton  Jean‐Luc Gardette
Affiliation:1. Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont‐Ferrand, BP 10448, F‐63000 Clermont‐Ferrand, France;2. CNRS, UMR 6296, ICCF, BP 80026, F‐63171 Aubiere, France
Abstract:Polyvinylalcohol (PVA) nanocomposites were prepared by a “one step” method based on the coprecipitation of layered double hydroxide (LDH) platelets in the polymer aqueous solution. The PVA/LDH nanocomposites displayed an exfoliated morphology and the concentration of LDH in the nanocomposite was evaluated by IR analysis. Moreover, it was shown that the PVA/LDH nanocomposites had an improved photostability over PVA, which makes this material a good candidate for coating applications. Further optimization will be considered to tune the polymer/LDH properties. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
Keywords:clay  composites  photochemistry  synthesis and processing  degradation
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