| 聚(2,5-二甲基对苯乙炔)前聚物的合成及表征 |
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| 引用本文： | 王建营,李银奎.聚(2,5-二甲基对苯乙炔)前聚物的合成及表征[J].化学世界,1999,40(7):373-375. |
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| 作者姓名： | 王建营 李银奎 |
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| 作者单位： | [1]国防科工委军事医学研究所 [2]国防科技大学材料工程与化学系 |
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| 摘 要： | 以对二甲苯为原料，经三步化学反应合成聚（２，５－二甲基－１，４－亚苯基－１′，２′－乙二撑－１′－氯化二乙锍盐），讨论了温度、气氛和溶剂对聚合反应的影响。产品的结构由ＩＲ和１ＨＮＭＲ光谱得到确认
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| 关 键 词： | 聚（2.5-二甲基-1.4-亚苯基-1'.2'－乙二撑-1'-氯化二乙锍盐） 预聚物路线合成 |
Synthesis and Characterization of Poly(2,5dimethyl1,4phenylene1,2ethylene1diethylsulphonium chloride) |
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| Wang Jianying\ Li Yinkui\ Long Yongfu\ Zhang Guangyou.Synthesis and Characterization of Poly(2,5dimethyl1,4phenylene1,2ethylene1diethylsulphonium chloride)[J].Chemical World,1999,40(7):373-375. |
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| Authors: | Wang Jianying\ Li Yinkui\ Long Yongfu\ Zhang Guangyou |
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| Affiliation: | Wang Jianying\ *Li Yinkui\ 1Long Yongfu\ 1Zhang Guangyou |
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| Abstract: | The precursor polymer of poly(2,5dimethylpphenylene vinylene)poly(2,5dimethyl1,4phenylene1,2ethylene1diethylsulphonium chloride) was synthesized by 3step reactions using pdimethylbenzene as raw material. Effect of temperature,atmosphere and solvent on the polymerization were discussed. The structure of the product was identified by IR and 1 H NMR. |
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| Keywords: | poly(2 5dimethyl1 4phenylene1 2ethylene1diethylsulphonium choride)precursor routesynthesis |
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