| 四氮杂杯[2]芳烃[2]三嗪叠氮化衍生物的合成及其与RDX的配合研究 |
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| 引用本文： | 王晶,曹端林,胡志勇,张文艳.四氮杂杯[2]芳烃[2]三嗪叠氮化衍生物的合成及其与RDX的配合研究[J].天津化工,2009,23(3):16-18. |
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| 作者姓名： | 王晶 曹端林 胡志勇 张文艳 |
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| 作者单位： | 中北大学化工与环境学院,山西,太原,030051 |
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| 摘 要： | 文合成了氮原子桥连杯2]芳烃2]三嗪化合物。室温下，以碳酸钾为缚酸剂，利用三聚氯氰和间苯二胺的亲核取代反应合成主体，并将其叠氮化，反应温度为40％。产物通过元素分析，红外光谱和氢谱对其结构进行了表征，并采用XRD对氮杂杯4]芳烃及其衍生物与黑索今的配合性能进行了表征分析，结果表明主客体之间发生了相互作用。
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| 关 键 词： | 超分子化学 杂原子杯芳烃 三聚氯氰 合成 |
Studies on synthesis of tetraazacalix[2]arene[2]triazine azides-derivative and it's derivation complex with RDX |
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| WANG Jing,CAO Duan-lin,HU Zhi-yong,ZHANG Wen-yan.Studies on synthesis of tetraazacalix[2]arene[2]triazine azides-derivative and it''s derivation complex with RDX[J].Tianjin Chemical Industry,2009,23(3):16-18. |
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| Authors: | WANG Jing CAO Duan-lin HU Zhi-yong ZHANG Wen-yan |
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| Affiliation: | (School of Chemical Engineering＆ Environment, North University of Chino, Shanxi Taiyuan 030051,China) |
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| Abstract: | We synthesized Aza-bridged calix2]arene2]triazines.At room temperature,Tetraazacalix2]arene2] triazine have been synthesized by m-phenylenediamine and cyanuric chloride,and potassium carbonate was taken as neutralisatal reagents.h was a nucleophillic substitution reaction.Then,it＇s azides was synthesized by sodium and Tetraazacalix 2]arene 2]triazine,at 40℃.The product was characterized by melting point,IR,element analysis and HNMR,we also investigated the complex by XRD.The experiment results showed that there was reciprocity between host and guest. |
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| Keywords: | superamolecules chemistry heteroatom-bridged calixarenes cyanuric chloride synthesis |
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