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乙烯齐聚法制取线性α-烯烃技术进展
引用本文:潘爱祥. 乙烯齐聚法制取线性α-烯烃技术进展[J]. 云南化工, 2007, 34(1): 80-83,85
作者姓名:潘爱祥
作者单位:德希尼布天辰化学工程(天津)有限公司上海分公司,上海,200031
摘    要:线性α-烯烃是重要的基本有机化工原料和精细化学品生产的中间体,在合成聚烯烃方面需求增长迅速。乙烯齐聚法主要包括烷基铝催化法、SHOP法和金属络合物催化法等三种工艺。本文对线性α-烯烃的应用以及近年来的技术进展做了详尽总结。鉴于我国目前尚无乙烯齐聚法生产α-烯烃的工业装置,笔者认为应该重视和加强这方面的研发工作。

关 键 词:乙烯  齐聚  线性α-烯烃  进展
文章编号:1004-275X(2007)01-0080-04
修稿时间:2006-05-17

Technological Advance on the Preparation of Linear α- olefin by Ethylene Oligomerization
Pan Aixiang. Technological Advance on the Preparation of Linear α- olefin by Ethylene Oligomerization[J]. Yunnan Chemical Technology, 2007, 34(1): 80-83,85
Authors:Pan Aixiang
Affiliation:Shanghai Office, Technip Tianchen Chemical Engineering Co. Ltd. , Shanghai 200031, China
Abstract:Linear α-olefin,an ever increasingly comonomer in polyethylene plays important role both as raw material in fundamental organic chemical industry and as intermediate in fine chemicals.The oligomerization process of ethylene to LAO consists of alkyl aluminium catalytic process,SHOP process and metal complex catalytic process.Application and patent technology of LAO were summarized,and the importance to strength R & D in China was put forward as there was no industrial application of ligomerization of ethylene to LAO in China yet.
Keywords:ethylene  oligomerization  linear α-olefin  advance
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